A practical guide to the maintenance of cooling water systems: biocide dosing, corrosion coupon analysis and purging optimization

Technical analysis: Cooling water treatment: biocide dosing, corrosion coupon analysis, and blowdown optimization

A practical guide to the maintenance of cooling water systems: biocide dosing, corrosion coupon analysis and purging optimization

1. Scope and purpose

This technical manual covers maintenance procedures for closed and open circulating cooling systems of industrial enterprises in accordance with ISO 9001, EN 13445 and DSTU B V.2.5-35:2007 standards. It is intended for reliability engineers, mechanics and water treatment operators who are responsible for preventing corrosion, scale formation and biofouling on heat exchange equipment (shell and tube heat exchangers, cooling towers, condensers).

Maintenance is performed in the case of scheduled maintenance (weekly, monthly and quarterly), as well as unscheduled when the heat transfer coefficient decreases by more than 15% or when the pressure drop on the heat exchangers increases above 0.8 bar.

2. Safety measures

DANGER WARNING!
  • Chemical hazard: Biocides and corrosion inhibitors are toxic and irritating substances. Be sure to use an acid-resistant rubber apron, rubber gloves (nitrile or neoprene), safety glasses and a full face shield according to EN 166.
  • Lockout/Tagout (LOTO): Prior to any work on metering pumps, purge lines, or removal of corrosion coupons, turn off power to actuators, close shut-off valves, and place "DO NOT OPERATE. People at Work" signs (ISO 3864 standard).
  • Pressurization: Before disassembling sampling assemblies or coupon mounting cells, depressurize the system to 0 bar and check that there is no residual pressure on the pressure gauge.

3. Necessary tools and materials

The name of the tool / materialTechnical specificationQuantity
Digital photocolorimeter / pH meterpH range 0-14, accuracy ±0.011 pc.
Laboratory scalesWeighing accuracy up to 0.1 mg1 pc.
Torque wrenchThe range is 10-50 Nm1 pc.
A set of combination keysSizes 10-32 mm1 set
Digital multimeter CAT III 600V (for testing metering pumps)1 pc.
Teflon tape (FUM)Thickness 0.1 mm, width 12 mm2 rolls
Corrosive couponsSteel St.3 / Stainless steel 1.4404 / BrassBy the number of points
Personal protective equipmentGOST EN 166, DSTU EN 374Set

4. Checklist before maintenance

Check elementWhat to checkAcceptance / rejection criteriaNotes
Dosing pumpsThe integrity of the membranes, the absence of leakageNo chemical leaks, pressure in the line 3.5 - 5.0 barCheck the tightness of the joints of PVC pipes
pH and conductivity sensorsCalibration and cleanliness of the glassThe calibration error is less than 2%. Absence of depositsUse buffer solutions pH 4.01, 7.01
A node of corrosion couponsThe integrity of the seals, the condition of the holderThe absence of thread corrosion, the presence of fluoroplastic gasketsThe flange tightening torque is no more than 25 Nm
Purge valveServiceability of the electric drive/pneumatic driveOpening/closing time less than 5 seconds, airtight in the closed positionCheck the signal from the conductometer

5. Step-by-step service procedure

  1. Preparation of the system and dosing equipment
    1. Put the biocide and inhibitor dosing pumps into manual mode (Manual) on the control panel (PLC).
    2. Purge the dispenser suction line to remove air blockages. The working pressure in the reagent supply line should be 4.0 ± 0.5 bar.
    3. Typical error: Starting dosing with the outlet valve closed leads to water hammer and rupture of the membrane of the dosing pump.
  2. Control and optimization of biocide dosing
    1. Take a water sample from the point after the cooler for analysis for total microbial count (TBC) and the presence of sulfate-reducing bacteria (SRB).
    2. According to the results of the analysis, adjust the dosage of the shock biocide. The concentration of free active chlorine or isothiazolinones in the system should be maintained at the level of 0.5 - 1.5 mg/l for 4 hours.
    3. Check the operation of the cyclic dosing timer (recommended frequency: 2 times a week for open systems).
  3. Disassembly and Analysis of Corrosion Coupons
    1. Close the stop valves on the bypass line of the corrosion coupon stand. Completely release the residual pressure through the drain valve.
    2. Remove the coupon holder using a 19 mm combination wrench. Fix the moment of unscrewing.
    3. Remove the coupons, rinse them with distilled water, dry them with filter paper and pack them in vacuum bags with silica gel for further weighing on a laboratory balance with an accuracy of 0.1 mg.
    4. Calculate the corrosion rate ($CR$) using the formula: $CR = (87.6 imes W) / (D imes A imes T)$, where $W$ is the mass loss (mg), $D$ is the metal density (g/cm³), $A$ is the surface area (cm²), $T$ is the exposure time (h). Permissible corrosion rate for carbon steel: less than 0.1 mm/year.
    5. Typical mistake: Touching the cleaned coupons with bare hands before weighing leaves greasy marks that distort the results of the weight loss analysis.
  4. Blowdown system optimization and adjustment
    1. Measure the electrical conductivity of circulating water using a portable conductometer. The maximum permissible value of electrical conductivity (evaporation coefficient $K = 3 - 4$) is usually 2500 - 3500 μS/cm depending on the quality of the feed water.
    2. Program the purge controller to maintain a given salinity threshold.
    3. Check the flow capacity of the purge solenoid valve. The valve opening time is regulated according to the laboratory analysis of chlorine ions ($Cl^-$).
    4. Tighten the bolts of the flange connections of the purge line with a torque wrench to a value of 22 Nm. Visually check for leaks at an operating pressure of 3.0 bar.

6. Checklist after completion of work

Test / CheckExpected resultActual resultStatus (Passed / Failed)
Checking the tightness of mainsNo leaks of water and chemicals at 5.0 bar
Dispensers work in automatic modeA signal from the feed flow meter activates the dispensers
Stability of pH indicatorsThe pH value is within 7.5 - 8.5
Purge levelElectrical conductivity below 3000 μS/cm

7. Search and troubleshooting

SymptomProbable nature of the malfunctionCorrective action
High corrosion rate (> 0.12 mm/year)Low corrosion inhibitor concentration or low pH (< 7.0)Check the inhibitor supply, increase the dosage of caustic soda to stabilize the pH
Intensive biofouling (slime in the cooling tower)Insufficient efficiency of the biocide, resistance of bacteriaChange the type of biocide (alternation of oxidizing and non-oxidizing reagents), carry out shock biocidal treatment
Scale formation on heat exchangersExcessive evaporation of water, malfunction of the purge valveReduce the evaporation cycle, calibrate the conductivity sensor, unlock the purge valve
The dosing pump does not pump the reagentAeration of the pump head or clogging of the check valveOpen the air deaeration valve on the pump head, rinse the non-return valve in a weak solution of hydrochloric acid

8. Recommended maintenance schedule

TaskFrequencyEstimated durationQualification level
Measurement of pH, conductivity, residual chlorineEvery day15 minutesInstallation operator
Checking the consumption of reagents and the presence of sedimentEvery week30 minutesService technician
Analysis of corrosion coupons and replacement of reagentsEvery month2 hoursMechanical engineer
Complete flushing of the system and disinfection with a biocideEvery 6 months8 hoursMaintenance team

9. Directory of spare parts

Description of the partTypical specificationCategory UNITEC
Membrane metering pumpQ = 10 l/h, P = 10 bar, PVDF/PTFEPumping equipment and dispensers
Electromagnetic solenoid valveDu 25, PN 16, 230V AC, FKM sealShut-off and regulating fittings
Conductivity sensor (conductivity meter)0 - 20,000 μS/cm, output 4-20 mAControl and measuring devices (KVP)
A set of corrosion couponsArt.3 / 1.4404, size 75x12.5x1.5 mmConsumables for laboratories
Dispenser check valvePVC body, Hastelloy springPipeline components

To order the necessary spare parts and consumables for cooling systems, visit the electronic catalog UNITEC-D.

10. Links

  • ISO 9001: Quality management systems. Requirements
  • EN 13445: Pressure vessels are not welded.
  • DSTU B V.2.5-35:2007: Water supply and sewerage. External networks and structures.
  • ISO 3864: Graphic symbols. Safety colors and safety signs.
  • OEM Technical Manuals for Industrial Cooling Towers and Heat Exchangers.

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